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KMID : 0903519970400060588
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Journal of the Korean Society of Agricultural Chemistry and Biotechnology
1997 Volume.40 No. 6 p.588 ~ p.592
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Synthesis and Application of New Type Organometallic Catalyst
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Abstract
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The new type ligand, bisphosphonites, were easily prepared through ligand exchange reaction of bis (diethylamino)phosphine with diols. These bisphosphonites reacted with (COD)²Rh^+BF₄^- to corresponding bisphosphonite-rhodium(I) comlexes, of which X-ray crystallography was for the first time investigated. This organometallic compound was applicated in hydroformylation reaction as catalyst, and proved to be very effective one.
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